MARC状态：审校 文献类型：西文图书 浏览次数：31
- 题名/责任者:
- Elements of molecular and biomolecular electrochemistry : an electrochemical approach to electron transfer chemistry / Jean-Michel Savéant and Cyrille Costentin.
- 版本说明:
- Second edition.
- 出版发行项:
- Hoboken, NJ : John Wiley & Sons Inc., 2019.
- ISBN:
- 9781119292333
- 载体形态项:
- xxiii, 616 pages : illustrations ; 24 cm
- 个人责任者:
- Savéant, Jean Michel, author.
- 附加个人名称:
- Costentin, Cyrille, 1972- author.
- 论题主题:
- Electrochemistry.
- 论题主题:
- Charge exchange.
- 论题主题:
- Chemical kinetics.
- 中图法分类号:
- O646
- 书目附注:
- Includes bibliographical references and index.
- 内容附注:
- Cover; Title Page; Copyright; Contents; Preface; Chapter 1 Single-Electron Transfer at an Electrode; 1.1 Introduction; 1.2 Cyclic Voltammetry of Fast Electron Transfers: Nernstian Waves; 1.2.1 One-Electron Transfer to Molecules Attached to the Electrode Surface; 1.2.2 One-Electron Transfer to Free-moving Molecules; 1.3 Technical Aspects; 1.3.1 The Cyclic Voltammetry Experiment -- Faradaic and Double-Layer Charging Currents. Ohmic Drop; 1.3.2 Other Techniques. Convolution; 1.4 Electron Transfer Kinetics; 1.4.1 Introduction; 1.4.2 Butler-Volmer Law and Marcus-Hush-Levich (MHL) Model
- 内容附注:
- 1.4.3 Extraction of Electron Transfer Kinetics from Cyclic Voltammetric Signals. Comparison with Other Techniques1.4.4 Experimental Testing of the Electron Transfer Models; 1.5 Successive One-Electron Transfers vs. Two-Electron Transfers; 1.5.1 Introduction; 1.5.2 Cyclic Voltammetric Responses: Convolution; 1.5.3 Response of Molecules Containing Identical and Independent Reducible or Oxidizable Groups; 1.5.4 An Example of the Predominating Role of Solvation: The Oxidoreduction of Carotenoids
- 内容附注:
- 1.5.5 An Example of the Predominating Role of Structural Changes: The Reduction of trans-2,3-Dinitro-2-buteneReferences; Chapter 2 Coupling of Electrode Electron Transfers with Homogeneous Chemical Reactions; 2.1 Introduction; 2.2 Establishing the Mechanism and Measuring the Rate Constants for Homogeneous Reactions by Means of Cyclic Voltammetry and Potential Step Chronoamperometry; 2.2.1 The EC Mechanism; 2.2.2 The CE Mechanism; 2.2.3 The Square Scheme Mechanism; 2.2.4 The ECE and DISP Mechanisms; 2.2.5 Electrodimerization; 2.2.6 Homogeneous Catalytic Reaction Schemes
- 内容附注:
- 2.2.6.1 Homogeneous Electron Transfer as the Rate-Determining Step2.2.6.2 Homogeneous Catalytic EC Mechanism; 2.2.6.3 Deactivation of the Mediator; 2.2.7 Electrodes as Catalysts: Electron-transfer Catalyzed Reactions; 2.2.8 Numerical Computations: Simulations, Diagnostic Criteria, Working Curves; 2.3 Product Distribution in Preparative Electrolysis; 2.3.1 Introduction; 2.3.2 General Features; 2.3.3 Product Distribution Resulting from Competition Between Follow-Up Reactions; 2.3.4 The ECE-DISP Competition; 2.3.5 Other Reactions Schemes
- 内容附注:
- 2.4 Classification and Examples of Electron-Transfer Coupled Chemical Reactions2.4.1 Coupling of Single Electron Transfer with Acid-Base Reactions; 2.4.2 Electrodimerization; 2.4.3 Electropolymerization; 2.4.4 Reduction of Carbon Dioxide; 2.4.5 H-Atom Transfer vs. Electron + Proton Transfer; 2.4.6 The SRN1 Substitution: Electrodes and Electrons as Catalysts; 2.4.7 Conformational Changes, Isomerization and Electron Transfer; 2.5 Redox Properties of Transient Radicals; 2.5.1 Introduction; 2.5.2 The Direct Electrochemical Approach; 2.5.3 Laser Flash Electron Injection
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